Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E     

Yoshiyuki Takahashi  Eiji Matsumoto  Yutaka W. Watanabe 《Journal of Oceanography》1999,55(6):717-729

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.  相似文献   

Simultaneous vertical measurements of in situ pH and CO2 in the sea using spectrophotometric profilers     

Yoshiyuki Nakano  Hideshi Kimoto  Shuichi Watanabe  Koh Harada  Yutaka W. Watanabe 《Journal of Oceanography》2006,62(1):71-81

We have developed new systems capable of profiling to >1000 m for measuring in situ pH and fugacity of CO₂ (fCO₂) in the ocean using spectrophotometric analysis (pH and CO₂ profilers). The in situ pH is determined by detecting the color change of the pH indicator (m-cresol purple). It can withstand ambient pressure to 1000 m depth. The CO₂ profiler analyzed in situ fCO₂ by detecting the change of pH in an inner solution, equilibrated with the seawater through a gas permeable membrane. It can be operated to 2500 m depth. We used an amorphous fluoropolymer tubing form of AF-2400 for the gas permeable membrane due to its high gas permeability coefficients. The inner solution was a mixture of 2 μM bromocresol purple (BCP) and 5 μM sodium hydroxide. This system gave us a response time of 1 minute, which is twice as fast as previous systems. The precisions of pH and CO₂ profilers were within 0.002 and 2.5% respectively. We have used these profilers to study the North Pacific, obtaining good agreement with the difference between the data from profilers and a discrete bottle of 0.002 ± 0.005 pH (SE, n = 25) and −0.4 ± 3 μatm (SE, n = 31).  相似文献   

Behavior of heavy metals and particulate matters in seawater expected from that of radioactive nuclides     

Shizuo Tsunogai  Yoshiyuki Nozaki  Masao Minagawa 《Journal of Oceanography》1974,30(6):251-259

Vertical profiles of²¹⁰Pb and²³⁰Th in the deep water were analyzed by using a simple one-dimensional model. Both nuclides are considered to settle down with the velocity of 1×10^–4 cm/sec. The diameter of particle corresponding to the velocity is calculated to be 5, while only about 10 % of the nuclides can be collected on filter paper with a pore size of 0.5. It is supposed that the nuclides exist in particulate materials which is changeable in size. This suggestion is supported from the following evidences. (1) The directly observed behavior of marine snow and the size distribution of particles observed with a coulter counter. (2) The existence of many chemical elements of which residence time is about 150 years. (3) Their possible existence as eutectic solid phases in the seawater. (4) The consistency of the observed accumulation rate of pelagic sediments with that estimated from the settling velocity. (5) The consistency of the decomposition rate of organic matter in the deep water estimated from the oxygen comsumption with that from the settling velocity.  相似文献   

Determination of thorium isotopes in seawater by moored MnO2-fiber method     

Nozaki  Yoshiyuki 《Journal of Oceanography》1983,39(3):129-135

A method is described for the determination of Th isotopes (²³²Th,²³⁰Th,²²⁸Th and²²⁷Th) in seawater through analysis of Th adsorbed on MnO₂-impregnated fiber that has been moored in the deep sea for up to 10 months. Since the MnO₂-fiber adsorbs Th from seawater at a constant rate, natural²³⁴Th can be used as a yield monitor by making a correction for its decay during the period of deployment. The results obtained by the method showed good reproducibility and accuracy. The method has the advantage over the chemical coprecipitation method that the time and labor for sampling and processing a large-volume of seawater is reduced.  相似文献   

Th and Pa isotopes in the waters of the western margin of the pacific near Japan: Evidence for release of228Ra and227Ac from slope sediments     

Yoshiyuki Nozaki  Han-Soeb Yangt 《Journal of Oceanography》1987,43(4):217-227

Using the moored MnO₂-fiber method, we have obtained 38 determinations of Th and Pa isotope concentrations from 18 sites along the margin of the western North Pacific near Japan, from water depths of 1,330 to 5,873 m. From our data, we are able to show that (1)²²⁸Ra and²²⁷Ac are being supplied to the seawater from the slope sediments of Honshu, Japan, (2) our²³⁰Th and²³¹Pa concentrations match those obtained byin situ pumping with a MnO₂-fiber adsorber in the Japan and Izu-Ogasawara trenches but are significantly higher than those from the Panama and Guatemala basins, and (3) our²³²Th concentrations show a similar systematic decrease with depth as do those of trace metals like Mn, Al, Te and Bi whose concentrations are strongly controlled by particulate matter scavenging.In contrast, our data fail to show (1) that enhanced removal of²³⁰Th and²³¹Pa by scavenging from the water column is taking place near the western margins and (2) that²³¹Pa is being removed in preference to²³⁰Th from the water column to the marginal sediments. This is probably due to rapid mixing of the deep waters as compared to the scavenging rates of²³⁰Th and²³¹Pa in the water column and at the sediment/seawater interface.  相似文献   

Radium isotopes in coastal and open ocean surface waters of the Western North Pacific   总被引：1，自引：0，他引：1  

Masatoshi Yamada  Yoshiyuki Nozaki 《Marine Chemistry》1986,19(4)

Using manganese-impregnated fiber extraction and high-efficiency gamma counting techniques, we measured the distribution of ²²⁸Ra and ²²⁶Ra in surface waters near the coast of Japan and in the western North Pacific. There is no evidence in our data that any significant amount of ²²⁸Ra is added to open ocean surface waters from the coastal waters around Tokyo Bay. High ²²⁸Ra concentrations (> 10 dpm/10³ kg), were observed along the Kuroshio Current as compared to < 2.5 dpm/10³ kg between 10° and 30°N of the central gyre, and hence the major source of ²²⁸Ra in the surface water is likely to be the East Asian continental shelf zones. A simple one-dimensional eddy diffusion and advection model is used to explain the observed decrease of ²²⁸Ra from coast to the open ocean. The model results indicate two mixing regimes across the Kuroshio Current System with apparent eddy diffusion coefficients of K_y = 4 × 10⁵ cm² s⁻¹ at distance y < 200 km from the coast, and K_y = 4 × 10⁷ cm² s⁻¹ at y > 200 km. Along 40°N where an eastward flow of the ‘Kuroshio Extension’ prevails, an advective flow of > 0.1 knot is consistent with the observation of nearly constant ²²⁸Ra along the track.The geographical distribution pattern of ²²⁸Ra is clearly different from that of atmospherically derived ²¹⁰Pb. Thus the ²²⁸Ra in surface water serves as a useful tracer that accompanies fluvially and coastally derived elements during their subsequent lateral transport toward the central gyre.  相似文献   

Reconstruction of pH in the Surface Seawater over the North Pacific Basin for All Seasons Using Temperature and Chlorophyll-<Emphasis Type="Italic">a</Emphasis>     

Yoshiyuki?NakanoEmail author  Yutaka?W.?Watanabe 《Journal of Oceanography》2005,61(4):673-680

We found a simple function of pH that relates to sea surface temperature (SST, K) and chlorophyll-a (Chl, µg l⁻¹) using measured surface seawater pH, SST and Chl data sets over the North Pacific: pH (total hydrogen scale at 2°C) = 0.01325 SST − 0.0253 Chl + 4.150 (R² = 0.95, p < 0.0001, n = 483). Moreover, evaluating the seasonal variation of pH based on this algorithm, we compared the measured pH with the predicted pH at the observational time series stations in subpolar and subtropical regions. The average of ΔpH (measured - predicted, n = 52) was 0.006 ± 0.022 pH. Therefore, the combination of SST and Chl can allow us to determine the spatiotemporal distribution of pH over the North Pacific. Using the climatological data sets of SST and Chl with our pH algorithms, we have described the seasonal distributions of pH at 25°C (pH₍₂₅₎) and pH in situ temperature (pH_(T)) over the North Pacific surface water.  相似文献   

Changes in the lower limit of mountain permafrost between 1973 and 2004 in the Khumbu Himal, the Nepal Himalayas   总被引：2，自引：0，他引：2  

Kotaro Fukui  Yoshiyuki Fujii  Yutaka Ageta  Katsuhiko Asahi 《Global and Planetary Change》2007,55(4):251-256

Because the Khumbu Himal of the Nepal Himalayas lacks long-term climate records from weather stations, mountain permafrost degradation serves as an important indicator of climate warming. In 1973, the permafrost lower limit was estimated to be 5200–5300 m above sea level (ASL) on southern-aspect slopes in this region. Using ground-temperature measurements, we examined the mountain permafrost lower limit on slopes with the same aspect in 2004. The results indicate that the permafrost lower limit was 5400–5500 m ASL in 2004. The permafrost lower limit was estimated to be 5400 to 5500 m on slopes with a southern aspect in the Khumbu Himal in 1991 using seismic reflection soundings. Thus, it is possible that the permafrost lower limit has risen 100–300 m between 1973 and 1991, followed by a stable limit of 5400 to 5500 m over the last decade. An increase in mean annual air temperature of approximately 0.2 to 0.4 °C from the 1970s to the 1990s has indicated a rise in the permafrost lower limit of 40 to 80 m at the Tibetan Plateau. The rise in the mountain permafrost lower limit in the Khumbu Himal exceeds that of the Tibetan Plateau, suggesting the possibility of greater climate warming in the Khumbu Himal.  相似文献   

理学ZSX系列X荧光光谱仪中文软件开发   总被引：3，自引：1，他引：3  

邓赛文  片冈由行 《岩矿测试》2001,20(3):226-233

介绍了日本理学ZSX系列X荧光光谱仪的特点和新开发的中文版软件的功能。  相似文献   

Tectonic setting of high-Mg andesite magmatism in the SW Japan arc: K–Ar chronology of the Setouchi volcanic belt     

Yoshiyuki Tatsumi  Naoto Ishikawa  Ken Anno  Kyoichi Ishizaka  Tetsumaru Itaya 《Geophysical Journal International》2001,144(3):625-631

  相似文献